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Chapter 2   Lecture 2 - Uncertainity and Quantum Waves

2.1   Properties of Classical Waves

2.1.1   Principle of Superposition

From the linearity of the wave equation it follows that at any point in space and time ( r , t ) the total amplitude is the sum of the contributing amplitudes.
A(r,t)=A1(r1,t)+A2(r2,t)+...     (2.1)
This leads to interference phenomena and can also apply to matter waves

2.1.2   Bandwidth Theorem and Diffraction

Consider an electromagnetic pulse A(t)

Figure 2.1 - An Electromagnetic Pulse
This can be constructed from an infinite sum of monochromatic components.
A(t)=
 
å
n
ansin(wnt) = ó
õ
a(w )sin(w t)dw     (2.2)
We can talk of a(w ) of begin a pulse spectrum.

Figure 2.2 - Pulse Spectrum
Equation 1.9 is a Fourier Transform linking w and t to a Fourier Pair. A mathematical property constraining Dw anf D t is
DwD t a     (2.3)
a is a number of order 1 (Gaussians 1/2 ) ® bandwidth limit or transform limit. Other quantities like x and k form an analagous pair and so likewise there will be a limit on the product
D kD x a     (2.4)
This is an equation describing diffraction To relate to matter waves we can use relations in equation 1.7 (de Broglie's Postulate)
E=w Þ D ED t
2
p= k Þ D pD x
2
    (2.5)
These are the uncertainity relations

2.2   Diffraction of a Quantum Wave

2.2.1   A Classical Wave


Figure 2.3 - Classical Diffraction Experiment
intensity µ |amplitude|2
Þ Iµ E2  (field amplitude)
I(q )µ sinc2 æ
ç
ç
è
ka
2
sinq ö
÷
÷
ø
    (2.6)
Where sinc x=sinx/x

2.2.2   A Quantum Wave

In QM we often deal with single particle matter waves therefore we call these quantum waves.

Figure 2.4 - Quantum Diffraction Experiment
After some time and by summing the number of hits in a single place across the plain of the detector array we recreate
sinc2 æ
ç
ç
è
ka
2
sinq ö
÷
÷
ø
and as for the probability for a single particle
P(q )µ sinc2 æ
ç
ç
è
ka
2
sinq ö
÷
÷
ø
    (2.7)
and so this can be made to be
probabilityµ|amplitude|2

2.3   Wave Function of a Matter Wave

Using this probabilistic interpretation we postulate the probability amplitude f(r,t) of a matter wave will be related to the probability of finding a particle at location ( r , t ).
P(r,t)=|f(r,t)|2=f(r,t)f*(r,t)     (2.8)

For a beam of particles of definite momentum p that propagate freely in the x direction, what is f(x,t) ? This means that is p is definite then from the uncertainity principle
D xD p
h
2
we can see all x values are equally probable as D p=0 . A mathematically consistent form is
f(x,t)=Ae
æ
ç
ç
è
p
 
x-
E
 
t ö
÷
÷
ø
 
    (2.9)
P(x,t)=f(x,t)f*(x,t)=A2
because
æ
è
e
q
 
e
-q
 
ö
ø
=1

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